![]() Method of producing composite articles from lignocellulose materials containing sugar
专利摘要:
A low cost process of making composite products from sugar containing lignocellulosic materials, such as sugarcane bagasse and stalks of sorghum, corn, sunflower, flax, and the like, utilizing the residual sugars as bonding and strengthening agent. Comminuted sugar containing lignocellulosic material wholly composed of or partially in combination with other lignocellulosic materials, in the absence of adhesive binders or bonding agents. is molded at a temperature of at least 180 DEG C and a pressure and for a time sufficient to compound the material into a composite product. The free sugars in lignocellulosic materials act as a thermosetting adhesive binder, and provide both bonding and strengthening effect. The composite thus products possess great strength and excellent dimensional stability. These results are obtained to the greatest extent when the lignocellulosic materials contain higher proportion of sugars. 公开号:SU1212318A3 申请号:SU833656698 申请日:1983-10-28 公开日:1986-02-15 发明作者:Сен Куо-Ченг 申请人:Содзи Охота (Фирма); IPC主号:
专利说明:
" The invention relates to the production of composite products from sugarcane marc, sorghum stalks, corn stalks, sunflower stalks, flax stalks and other lignocellulose materials, especially non-wood plants, containing sugars, carbohydrates or sugars, which are soluble in water and easily extracted. The purpose of the invention is to simplify the process by eliminating the processing of particles of a material by a binder. The invention is illustrated by the following examples. Example 1. Dried squeeze of sugar cane with a moisture content of 3.8% is obtained at a standard processing plant. You have a fat content of 7.2% by weight of water-soluble substances, of which 4.7% comes from low molecular weight sugars (e.g. glucose). In addition, the squeeze contains about 70% genuine fiber and 30% of the core. The squeeze is crushed with a hammer mill to produce two particle fractions. The particles passing through the 16th mesh sieve are used for the front layer, and the particles larger than 16th mesh are used as the central layer of the material dp of the three-layer mat. Attitudes of the front and central layers calculated on a dry weight of 1: 1. From the mat get a board size Content, based on the weight of dry fiber marc. 50 Each batch of marc is made with boards of 500 x X 500 x 11.1 mm and density of 0.70 using three different pressing temperatures (l80, 210 and 240 s), two different pressing times (10 and 20 minutes, and at pressing 3.4 MPa. ten 12123182 500x500x11.1 mm by hot pressing for 12 minutes to a specific weight of 0.72 at 235 ° C and a increase of 2.8 MPa. In the process of hot pressing, apart from moisture, a certain amount of substances in the form of steam and various foams occurs (the weight loss is 8.4%, which is significantly more than the moisture content in the mat). The modulus of elasticity of the finished product is MOR 16.3 MPa and the modulus of elasticity MY 3.8 GPa. five 0 0 5 five PRI mme R 2. Fresh pomace sugar cane, obtained from a sugar cane separator, is treated to remove the sugars by boiling in water. Three batches of marc are subjected to boiling for 5, 10 and 30 minutes, respectively, the fourth batch is not boiled (control). After boiling, the squeeze is dried to a moisture content of 8% and then crushed out with a hammer mill into fractions of ± 20 mesh, obtained using a sieve. Chemical analysis indicates that the content of residual sugars is inversely proportional to the boiling time of the sample. The results also show an almost linear relationship between the amount of water-soluble substances and the residual. sugars. Table 1 presents the results of boiling treatment. Table 1 The moisture content in the front layer of the board is 9, at the core of the board - 3.0%. The ratio of the dry weight of the front part and the core of the mat is 55 lts 1: 1. The properties of the boards are presented in table 2. OO A about cxi - OFCh r CO tM 00 r- i - - OFP CTi f r 00 - T in 1L - r m vO r vO G- rs r H about CM CM m CM N "one 1L h o CM r f t- CM r about oh oh sd - Ltd cm I 0) lou t; " Os oh s нX X - Oso " ted 0) S V-X Ю 5В vO ft - r l about go ) rO- " --00 - 00 M CO en rr " Oto “H - - - o fvj-, vO vO “L RCh” - - - "N CM fO o s n vO vO yi r o about Go VO MF o o vf vo. f - U vo About in "FM G-.4t about ro ъ in CO t CO CTi with -st "About 00 about -" about CM in CO CM CO "H r - about l m O T about 00 sh h st 04 "S about 00 k 00 in 00 xT CM - o ate o u - - 00 so about by w g "M g in sh sh sh g I-. in 1 go g 1L f. Go 1. about g "P year 1L t cm g oh oh -GM oh oh -Ism oh oh -cm oh oh oh - see - about about 00 about cm oh - see about 00 in cm there about iri Yu oo sjts er 00 r D) Vd CN O vO A rin M 00 oo H oo oo vO r o VO n one fn f about CN About CN ABOUT -cf CN in CN - CO CO er oo vo r cvj - “-I -“. vf 00 rn YU GO in N Ti mid N CN VO vO CN r cy CN 00 00 CN CN vD About about CO ro 41- oh oh CM-, oh oh CN-I about CN About 00 CN About f Cvj From the results shown in Table 2, it can be seen that the properties of the boards improve when the sugar content of the squeeze increases. Increasing the pressing temperature and increasing the pressing time also improves the quality of the board. Furniture squeeze board has a dense smooth surface and dark brown color mainly due to very fine particles and high sugar and moisture content in the front layer of the mat. Froze Sweet weed stalks, which contain about 18% low molecular weight sugars, are dried to a moisture content of 3%, crushed with a hammer mill and passed through a 20 mesh sieve. From this base, a board is sized 500x500 x X 11.1 mm, density 0.74 at 235 C and a pressure of 2.8 MPa for 10 minutes. Tests show that the MOR dry board is 18.5 MPa wet 88 9.2 MPa, internal bond strength 480 kPa. PRI me R 4. Corn stalks containing 12% soluble substances or about 7% low molecular weight sugar, dried to a moisture content of 3%, crushed with a hammer mill and passed through a 20 mesh sieve. From this base is made board size 500x500x11.1 mm, density 0.82. The tests show that the MOR of a dry board is 14.3 MPa, a wet one is 7.4 MPa, and the internal bond strength is 320 kPa. Thus, the invention makes it possible to manufacture composite products with a significant simplification of the technological process by eliminating the processing of particles of material by the binder.
权利要求:
Claims (1) [1] METHOD FOR PRODUCING COMPOSITE PRODUCTS FROM LIGNO CELLULAR MATERIALS CONTAINING SUGAR, including grinding material into particles and drying, particle fractionation, molding into a mat and hot pressing, characterized in that, in order to simplify the technological process by excluding the processing of material particles with a binder, fibers, and hot pressing is carried out at 180-240 C for 10-20 minutes. >
类似技术:
公开号 | 公开日 | 专利标题 RU2075384C1|1997-03-20|Method of manufacturing composite materials from lignocellulose raw material Widyorini et al.2005|Manufacture and properties of binderless particleboard from bagasse I: effects of raw material type, storage methods, and manufacturing process EP0492016B1|2002-09-18|Thermosetting resin material and composite products from lignocellulose US4627951A|1986-12-09|Process for manufacturing composite products from lignocellulosic materials SU1212318A3|1986-02-15|Method of producing composite articles from lignocellulose materials containing sugar US4364979A|1982-12-21|Composition board Lamaming et al.2014|Measurement of some properties of binderless particleboards made from young and old oil palm trunks CN1275750C|2006-09-20|Dry method for preparing cotton stalk fibrous board US2485587A|1949-10-25|Sheet lumber US2198269A|1940-04-23|Manufacture of compressed cellulosic or wood products US3504073A|1970-03-31|Method of preparing fiber boards RU2166521C2|2001-05-10|Method of manufacturing wood particle boards CA1211913A|1986-09-30|Process for manufacturing composite products fromlignocellulosic materials US3130114A|1964-04-21|Process of manufacturing fibreboards and pressings from lignocellulose material Widyorini et al.2018|Properties of citric acid-bonded composite board from elephant dung fibers US2798019A|1957-07-02|Structural board US2754728A|1956-07-17|Raintable hardboard and process of making the same DE10164659C2|2003-10-30|Binder-free fiber insulation and process for its production DE875137C|1953-04-30|Process for the production of fiberboard JPH10183500A|1998-07-14|Cellulosic molding product US2685529A|1954-08-03|Lignocellulose board US2581654A|1952-01-08|Dry process for making composite consolidated products with controlled presteaming of the raw materials DE2744425C2|1983-12-01|Dry process for the production of molded fiber bodies from plant-based lignocellulose-containing material that differs from trunk wood material, as well as a device for carrying out this process DE898964C|1953-12-07|Process for the production of lightweight building materials from waste wood CN85101499A|1987-01-31|Produce the production process of synthetic by lignocellulosic materials
同族专利:
公开号 | 公开日 GB8323003D0|1983-09-28| DK554583D0|1983-12-01| MX172616B|1994-01-03| BR8306450A|1985-03-12| GB2142943B|1987-03-25| KR850001345A|1985-03-18| NL8302960A|1985-02-01| IT8323636D0|1983-11-08| GB2142943A|1985-01-30| IN161051B|1987-09-26| KR920000756B1|1992-01-21| IT1169684B|1987-06-03| FR2549768A1|1985-02-01| JPS6030309A|1985-02-15| ZA838301B|1984-07-25| DK554583A|1985-01-08| PH19188A|1986-01-23| DE3333032A1|1985-01-24|
引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题 RU2458148C2|2010-09-21|2012-08-10|Российская академия сельскохозяйственных наук Государственное научное учреждение Всероссийский научно-исследовательский институт электрификации селького хозяйства Российской академии сельскохозяйственных наук |Method for production of cow parsnip white sugar|LU30302A1| US2402554A|1936-05-25|1946-06-25|Celotex Corp|Molded product and method of making| GB497477A|1937-03-16|1938-12-16|Masonite Corp|Improvements relating to the manufacture of moulded products from raw ligno-cellulose| FR1460600A|1965-07-19|1966-03-04|Processing of sugar cane to obtain construction materials as by-products| DE1905054A1|1968-02-05|1969-08-21|Dierks Forests Inc|Thermosetting saccharide-based binder| DK129401B|1969-02-14|1974-10-07|Forskningsinst For Handels Og|Method of making particle board.| CA1058499A|1974-02-22|1979-07-17|John Stofko|Bonding of solid lignocellulosic material| ZA785579B|1977-10-04|1980-05-28|Jansky J|Method of bonding solid lignocellulosic materials| JPS5914338B2|1978-03-06|1984-04-04|Kanadeian Patentsu Ando Dev Ltd| SE399015B|1976-10-06|1978-01-30|Reinhall Rolf|WAY TO MAKE FIBER PLATES| GB1599215A|1978-05-26|1981-09-30|London & Malaga Board Co Ltd|Process for making a building board|FR2723328B1|1994-08-03|1996-10-31|Lacroix Soc E|COMPOSITION FOR AGGLOMERATED PRODUCT COMPRISING A VEGETABLE FILLER AND SUGAR, AGGLOMERATED PRODUCT AND ITS PREPARATION METHOD| JPH11318669A|1997-12-16|1999-11-24|Changrong Wang|Manufacturing of packaging material and sheet from stem of plant| CN101733808B|2008-11-07|2014-11-26|北京环能海臣科技有限公司|Straw section with waterproof skin compounded on surface| WO2013099364A1|2011-12-28|2013-07-04|もったいないバイオマス株式会社|Cholesterol excretion promoter and neutral fat excretion promoter each utilizing inner stem fiber of sunflower| WO2013190777A1|2012-06-19|2013-12-27|パナソニック株式会社|Bagasse molding| ES2390853B2|2012-07-30|2013-03-19|Universidad Miguel Hernández De Elche|Manufacturing process of particle board of lignocellulosic material| EP3587531B1|2017-02-24|2022-01-05|Panasonic Intellectual Property Management Co., Ltd.|Method of manufacturing a wooden board by heat press molding with an adhesive| CN110405900A|2018-04-27|2019-11-05|中国科学院大连化学物理研究所|The method for preparing environment protection biological plate as raw material using the furfural dregs of lignocellulosic| CN109571703A|2018-12-27|2019-04-05|天津海源汇科技有限公司|It is a kind of for the auxiliary agent of artificial board of straw and the preparation method of artificial board of straw|
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申请号 | 申请日 | 专利标题 JP58124224A|JPS6030309A|1983-07-07|1983-07-07|Manufacture of composite product from lignocellulose material| 相关专利
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